Bi- and tri-dentate imino-based iron and cobalt pre-catalysts for ethylene oligo-/polymerization

Recent progress on the use of iron and cobalt complex pre-catalysts for ethylene reactivity is reviewed. The review is organized in terms of the denticity of the chelate ligands employed, with particular reference to the influence of the ligand frameworks and their substituents on the catalytic performance for ethylene oligomerization/polymerization catalysis. The majority of the systems bear tri-dentate ligation at the iron/cobalt centre, though it is clear that bi-dentate iron/cobalt complex pre-catalysts have also attracted significant attention. Such systems produce in most cases highly linear products ranging from oligomeric α-olefins to high molecular weight polyethylene, and as such are promising candidates for both academic and industrial considerations

Chronology of the Basalt Units Surrounding Chang’e-4 Landing Area

The Chang’e-4 (CE-4) lunar probe, the first soft landing spacecraft on the far side of the Moon, successfully landed in the Von Kármán crater on 3 January 2019. Geological studies of the landing area have been conducted and more intensive studies will be carried out with the in situ measured data. The chronological study of the maria basalt surrounding the CE-4 landing area is significant to the related studies. Currently, the crater size-frequency distribution (CSFD) technique is the most popular method to derive absolute model ages (AMAs) of geological units where no returned sample is available, and it has been widely used in dating maria basalt on the lunar surface. In this research, we first make a mosaic with multi-orbital Chang’e-2 (CE-2) images as a base map. Coupled with the elevation data and FeO content, nine representative areas of basalt units surrounding the CE-4 landing area are outlined and their AMAs are derived. The dating results of the nine basalt units indicate that the basalts erupted from 3.42 to 2.28 Ga ago in this area, a period much longer than derived by previous studies. The derived chronology of the above basalt units establishes a foundation for geological analysis of the returned CE-4 data

Infectious Disease in a Warming World: How Weather Influenced West Nile Virus in the United States (2001–2005)

Background: The effects of weather on West Nile virus (WNV) mosquito populations in the United States have been widely reported, but few studies assess their overall impact on transmission to humans. Objectives: We investigated meteorologic conditions associated with reported human WNV cases in the United States. Methods: We conducted a case–crossover study to assess 16,298 human WNV cases reported to the Centers for Disease Control and Prevention from 2001 to 2005. The primary outcome measures were the incidence rate ratio of disease occurrence associated with mean weekly maximum temperature, cumulative weekly temperature, mean weekly dew point temperature, cumulative weekly precipitation, and the presence of ≥ 1 day of heavy rainfall (≥ 50 mm) during the month prior to symptom onset. Results: Increasing weekly maximum temperature and weekly cumulative temperature were similarly and significantly associated with a 35–83% higher incidence of reported WNV infection over the next month. An increase in mean weekly dew point temperature was significantly associated with a 9–38% higher incidence over the subsequent 3 weeks. The presence of at least 1 day of heavy rainfall within a week was associated with a 29–66% higher incidence during the same week and over the subsequent 2 weeks. A 20-mm increase in cumulative weekly precipitation was significantly associated with a 4–8% increase in incidence of reported WNV infection over the subsequent 2 weeks. Conclusions: Warmer temperatures, elevated humidity, and heavy precipitation increased the rate of human WNV infection in the United States independent of season and each others’ effects

Small global-mean cooling due to volcanic radiative forcing

In both the observational record and atmosphere-ocean general circulation model (AOGCM) simulations of the last ∼∼ 150 years, short-lived negative radiative forcing due to volcanic aerosol, following explosive eruptions, causes sudden global-mean cooling of up to ∼∼ 0.3 K. This is about five times smaller than expected from the transient climate response parameter (TCRP, K of global-mean surface air temperature change per W m−2 of radiative forcing increase) evaluated under atmospheric CO2 concentration increasing at 1 % yr−1. Using the step model (Good et al. in Geophys Res Lett 38:L01703, 2011. doi:10.​1029/​2010GL045208), we confirm the previous finding (Held et al. in J Clim 23:2418–2427, 2010. doi:10.​1175/​2009JCLI3466.​1) that the main reason for the discrepancy is the damping of the response to short-lived forcing by the thermal inertia of the upper ocean. Although the step model includes this effect, it still overestimates the volcanic cooling simulated by AOGCMs by about 60 %. We show that this remaining discrepancy can be explained by the magnitude of the volcanic forcing, which may be smaller in AOGCMs (by 30 % for the HadCM3 AOGCM) than in off-line calculations that do not account for rapid cloud adjustment, and the climate sensitivity parameter, which may be smaller than for increasing CO2 (40 % smaller than for 4 × CO2 in HadCM3)

Gold Nanoparticle Enabled Localized Surface Plasmon Resonance on Unique Gold Nanomushroom Structures for On‐Chip CRISPR‐Cas13a Sensing

Abstract A novel localized surface plasmon resonance (LSPR) system based on the coupling of gold nanomushrooms (AuNMs) and gold nanoparticles (AuNPs) is developed to enable a significant plasmonic resonant shift. The AuNP size, surface chemistry, and concentration are characterized to maximize the LSPR effect. A 31 nm redshift is achieved when the AuNMs are saturated by the AuNPs. This giant redshift also increases the full width of the spectrum and is explained by the 3D finite‐difference time‐domain (FDTD) calculation. In addition, this LSPR substrate is packaged in a microfluidic cell and integrated with a CRISPR‐Cas13a RNA detection assay for the detection of the SARS‐CoV‐2 RNA targets. Once activated by the target, the AuNPs are cleaved from linker probes and randomly deposited on the AuNM substrate, demonstrating a large redshift. The novel LSPR chip using AuNP as an indicator is simple, specific, isothermal, and label‐free; and thus, provides a new opportunity to achieve the next generation multiplexing and sensitive molecular diagnostic system

Restoring Holographic Dark Energy in Brane Cosmology

We present a generalized version of holographic dark energy arguing that it must be considered in the maximally subspace of a cosmological model. In the context of brane cosmology it leads to a bulk holographic dark energy which transfers its holographic nature to the effective 4D dark energy. As an application we use a single-brane model and we show that in the low energy limit the behavior of the effective holographic dark energy coincides with that predicted by conventional 4D calculations. However, a finite bulk can lead to radically different results.Comment: 11 pages, version published in Phys. Lett.